5-((Dimethylamino)methyl)-2-furanmethanol → Ranisen

HRID 65761

反応式

HRID 65761 の反応式
[SH:1][CH2:2][CH2:3][NH:4][C:5]([NH:10][CH3:11])=[CH:6][N+:7]([O-:9])=[O:8].[CH3:12][N:13]([CH2:15][C:16]1[O:20][C:19]([CH2:21]O)=[CH:18][CH:17]=1)[CH3:14]>Cl.O.C(=O)([O-])[O-].[K+].[K+]>[CH3:12][N:13]([CH2:15][C:16]1[O:20][C:19]([CH2:21][S:1][CH2:2][CH2:3][NH:4][C:5]([NH:10][CH3:11])=[CH:6][N+:7]([O-:9])=[O:8])=[CH:18][CH:17]=1)[CH3:14]

参加物

6

反応物 2

HCID 849065-((Dimethylamino)methyl)-2-furanmethanolHCID 181798N-(2-Mercaptoethyl)-N'-methyl-2-nitro-1,1-ethenediamine

生成物 1

HCID 5039Ranisen

試薬・触媒・溶媒 3

HCID 313Hydrochloric Acid溶媒HCID 962Water溶媒HCID 11430Potassium Carbonate溶媒

実験手順

N-(2-Mercaptoethyl)-N'-methyl-2-nitro-1,1-ethenediamine (354 mg) in concentrated hydrochloric acid (2 ml) was added dropwise to 5-(dimethylamino)methyl-2-furanmethanol (428 mg) at 0°. After standing at 0° for 7 days the reaction was diluted with water (3 ml), excess potassium carbonate was added and the solid extracted with ethyl acetate (50 ml).

後処理

  1. additionwas added
  2. extractionthe solid extracted with ethyl acetate (50 ml)

出典と根拠

ORDレコード
ord-19209aada948472496e2dc6b9871a0e4
出典データセット
uspto-grants-1978_12
特許番号
US04128658

関連ノート

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