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Dimethylformamide dimethyl acetal → 1,4,8-Triazatricyclo[6.3.1.04,12]dodecane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethylformamide dimethyl acetal | HCID 78373 | — |
| 反応物 | 1,4,8-Triazacycloundecane | HCID 398742 | — |
| 生成物 | 1,4,8-Triazatricyclo[6.3.1.04,12]dodecane | HCID 12641658 | 81.8% |
反応手順
In a manner similar to that of Example 1 (C), 5.28 g (33.6 mmol) of 1,4,8-triazacycloundecane and 4.00 g of dimethylformamide dimethyl acetal were reacted to give 4.59 g of 1,4,8-triazatricyclo[6.3.1.04,12 ]dodecane as a clear, colorless liquid, bp 80°-82° (three fractions) (1.2 mm), nD24 = 1.5182. A fraction boiling at 82° was analyzed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04130715 |
| 出典データセット | uspto-grants-1978_12 |
| ORD ID | ord-141a818fb3f74ff09394c0b370e6a40e |
| 出典メモ | uspto-grants-1978_12 |