化工社化工社 化学情報印刷レポート · 研究参考用
Dimethylformamide dimethyl acetal → Hexahydro-1H,4H,7H-3a,6a,9a-triazaphenalene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dimethylformamide dimethyl acetal | HCID 78373 | — |
| 反応物 | 1,5,9-Triazacyclododecane | HCID 470778 | — |
| 生成物 | Hexahydro-1H,4H,7H-3a,6a,9a-triazaphenalene | HCID 12641659 | 73.1% |
反応手順
In a manner similar to that of Example 1 (C), 5.00 g (29.2 mmol) of 1,5,9-triazacyclododecane and 3.48 g of dimethylformamide dimethyl acetal were reacted to give 3.87 g of 1,5,9-triazatricyclo[7.3.1.05,13 ]tridecane as a clear, colorless liquid, bp 93° (three fractions) (0.35 mm), which solidified on standing at room temperature. One fraction was analyzed.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04130715 |
| 出典データセット | uspto-grants-1978_12 |
| ORD ID | ord-d742f01c8a9a451f8198c8a3497b4046 |
| 出典メモ | uspto-grants-1978_12 |