9,10-Dimethylanthracene → Anthracene, 9,10-dihydro-9,10-dimethyl-

HRID 66272

反応式

HRID 66272 の反応式
[CH3:1][C:2]1[C:3]2[C:8]([C:9]([CH3:16])=[C:10]3[C:15]=1[CH:14]=[CH:13][CH:12]=[CH:11]3)=[CH:7][CH:6]=[CH:5][CH:4]=2>[Cr]([O-])([O-])=O.[Cu+2].C1(C)C=CC=CC=1>[CH3:1][CH:2]1[C:3]2[CH:4]=[CH:5][CH:6]=[CH:7][C:8]=2[CH:9]([CH3:16])[C:10]2[C:15]1=[CH:14][CH:13]=[CH:12][CH:11]=2

参加物

4

反応物 1

HCID 130769,10-Dimethylanthracene

生成物 1

HCID 606352Anthracene, 9,10-dihydro-9,10-dimethyl-収率 8%

試薬・触媒・溶媒 2

HCID 178505374HCID 178505374、化合物触媒HCID 1140Toluene溶媒

実験手順

9,10-Dihydro-9,10-dimethylanthracene was prepared by hydrogenation of 9,10-dimethylanthracene with Girdler G-22 copper chromite catalyst in toluene at 120° C. and 1500 psi for 1 hour. The mixtures resulting from five such runs were combined and filtered, and the off-white solid product was isolated by evaporating the solvent. It was characterized by nmr spectroscopy.

後処理

  1. customThe mixtures resulting from five such runs
  2. filtrationfiltered
  3. customthe off-white solid product was isolated
  4. customby evaporating the solvent

出典と根拠

ORDレコード
ord-33838fd7755847479484c70ff8d9c312
出典データセット
uspto-grants-1978_12
特許番号
US04131646

関連ノート

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