2,4-Di-tert-butylphenol → 2,4-Di-tert-butyl-6-(1-(4-methoxyphenyl)ethyl)phenol, 4b

HRID 66626

反応式

HRID 66626 の反応式
[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[CH:7][C:6]=1[OH:15])([CH3:4])([CH3:3])[CH3:2].[CH3:16][CH:17](O)[C:18]1[CH:23]=[CH:22][C:21]([O:24][CH3:25])=[CH:20][CH:19]=1>>[C:11]([C:9]1[CH:10]=[C:5]([C:1]([CH3:4])([CH3:3])[CH3:2])[C:6]([OH:15])=[C:7]([CH:17]([CH3:16])[C:18]2[CH:23]=[CH:22][C:21]([O:24][CH3:25])=[CH:20][CH:19]=2)[CH:8]=1)([CH3:14])([CH3:13])[CH3:12]

参加物

3

反応物 2

HCID 73112,4-Di-tert-butylphenolHCID 1011481-(4-Methoxyphenyl)ethanol

生成物 1

HCID 1000462,4-Di-tert-butyl-6-(1-(4-methoxyphenyl)ethyl)phenol, 4b

実験手順

Similarly, 4,6-di-t-butyl-2-(α-methyl-4-methoxybenzyl) phenol was prepared from 2,4-di-t-butylphenol and α-methyl-4-methoxybenzyl alcohol. A yellow oil (b.p. 180° at 1.0 mm Hg) which crystallized was obtained. The product was recrystallized from methanol to give colorless needles melting at room temperature (Found: C, 81.0; H, 9.45 Calc. for C23H32O2 : C, 81.1; H, 9.47%). The pmr spectrum determined as above exhibited the following: δ1.35, 9H, S; δ1.37, 9H, S; δ1.63, 3H, D (J=7 Hz); δ3.78, 3H, S; δ4.17, Q, 1H (J=7 Hz); δ4.62, 1H, S; δ6.84, 2H, D (J=8 Hz); δ7.10-7.30, 4H, M.

後処理

  1. customA yellow oil (b.p. 180° at 1.0 mm Hg) which crystallized
  2. customwas obtained
  3. customThe product was recrystallized from methanol

出典と根拠

ORDレコード
ord-9094703b978a48cf8dc71596c05edb1a
出典データセット
uspto-grants-1982_08
特許番号
US04342777

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