Bromine → 1-Bromo-3-triphenylmethoxy-trans-1-nonene

HRID 67026

反応式

HRID 67026 の反応式
[C:1]1([C:7]([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)([C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[O:8][CH:9]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[C:10]#[CH:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.C(BC(C(C)C)C)(C(C)C)C.[Br:41]Br>>[Br:41]/[CH:11]=[CH:10]/[CH:9]([O:8][C:7]([C:1]1[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1)([C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)[C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1)[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

参加物

4

反応物 3

HCID 24408BromineHCID 192733Bis(1,2-dimethylpropyl)boraneHCID 204657223-Triphenylmethoxy-1-nonyne

生成物 1

HCID 204655201-Bromo-3-triphenylmethoxy-trans-1-nonene

実験手順

Treatment of 3-triphenylmethoxy-1-nonyne (Example 128) with disiamylborane and the bromine by the procedure described in Example 1173 is productive of the title compound.

出典と根拠

ORDレコード
ord-9a4274936f6441fe8affb6c22beeffe7
出典データセット
uspto-grants-1982_08
特許番号
US04343949

関連ノート

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