2-Tolyl isocyanate → Benzenamine, N,N'-methanetetraylbis(2-methyl-

HRID 67035

反応式

HRID 67035 の反応式
[C:1]1([CH3:10])[C:2]([N:7]=[C:8]=O)=[CH:3][CH:4]=[CH:5][CH:6]=1>C(=O)=O>[C:1]1([CH3:10])[CH:6]=[CH:5][CH:4]=[CH:3][C:2]=1[N:7]=[C:8]=[N:7][C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][C:1]=1[CH3:10]

参加物

3

反応物 1

HCID 691942-Tolyl isocyanate

生成物 1

HCID 102025Benzenamine, N,N'-methanetetraylbis(2-methyl-収率 85.8%

試薬・触媒・溶媒 1

HCID 280Carbon Dioxide溶媒

実験手順

133 g of o-tolylisocyanate and 5 g of solid, insoluble catalyst from Example 1a were heated together to 180° C. with stirring. After the evolution of 12.3 liters of carbon dioxide, which took place within 1.5 hours, the catalyst was suction filtered and the filtrate distilled. 95.3 g of di-o-tolyl-carbodiimide, b.p. 135°-137° C./0.1 Torr were obtained (87% of the theory).

後処理

  1. customwithin 1.5 hours
  2. filtrationfiltered
  3. distillationthe filtrate distilled

出典と根拠

ORDレコード
ord-85c2942e9f2541e99cc5825fb232fb2c
出典データセット
uspto-grants-1982_08
特許番号
US04344855

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