化工社化工社 化学情報印刷レポート · 研究参考用
17beta-Acetoxy-1alpha-methyl-17alpha-n-propyl-5alpha-androstan-3-one → 17beta-Acetoxy-1alpha-methyl-17alpha-n-propyl-5alpha-androstan-3beta-ol
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 17beta-Acetoxy-1alpha-methyl-17alpha-n-propyl-5alpha-androstan-3-one | HCID 13020886 | — |
| 反応物 | Lithium tri-tert-butoxyaluminohydride | HCID 16710494 | — |
| 生成物 | 17beta-Acetoxy-1alpha-methyl-17alpha-n-propyl-5alpha-androstan-3beta-ol | HCID 70360261 | 64.7% |
反応手順
1.0 g of 17β-acetoxy-1α-methyl-17α-n-propyl-5α-androstan-3-one is reacted as described in Example 6 with lithium tri-tert.-butoxyaluminum hydride and worked up. After chromatography on silica gel, 650 mg of 17β-acetoxy-1α-methyl-17α-n-propyl-5α-androstan-3β-ol is obtained as an oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04344941 |
| 出典データセット | uspto-grants-1982_08 |
| ORD ID | ord-e41a7caf7c83446eabe7ce3a36ff9a8f |
| 出典メモ | uspto-grants-1982_08 |