Tert-Butylhydroquinone → tert-Butyl-1,4-benzoquinone

HRID 67152

反応式

HRID 67152 の反応式
[C:1]([C:5]1[CH:11]=[C:10]([OH:12])[CH:9]=[CH:8][C:6]=1[OH:7])([CH3:4])([CH3:3])[CH3:2]>[O-2].[O-2].[Mn+4].C1(C)C=CC=CC=1>[C:1]([C:5]1[C:6](=[O:7])[CH:8]=[CH:9][C:10](=[O:12])[CH:11]=1)([CH3:4])([CH3:2])[CH3:3]

参加物

4

反応物 1

HCID 16043Tert-Butylhydroquinone

生成物 1

HCID 19211tert-Butyl-1,4-benzoquinone収率 80%

試薬・触媒・溶媒 2

HCID 178418406HCID 178418406、化合物触媒HCID 1140Toluene溶媒

反応条件

温度
70 °C

実験手順

16.6 g (0.10 mol) of 2-tert-butylhydroquinone was placed in a 200 cc 3-neck flask. After adding 17.4 g (0.20 mol) of powdery manganese dioxide, 100 cc of toluene was added thereto, and the mixture was heated with stirring. The temperature was maintained at 70° C. for 3 hours. After cooling to room temperature, the manganese dioxide was removed by filtration by means of suction using Celite as a filter aid. Then the manganese dioxide was washed with 50 cc of toluene, and the toluene was evaporated to dryness, by which 2-tert-butyl-1,4-benzoquinone was obtained. The yield was 80% and the melting point was 48°-50° C.

後処理

  1. additionwas added
  2. temperaturethe mixture was heated
  3. temperatureAfter cooling to room temperature
  4. customthe manganese dioxide was removed by filtration by means of suction
  5. washThen the manganese dioxide was washed with 50 cc of toluene
  6. customthe toluene was evaporated to dryness, by which 2-tert-butyl-1,4-benzoquinone
  7. customwas obtained

出典と根拠

ORDレコード
ord-5837863e67dc4d6886cf275d938e21dc
出典データセット
uspto-grants-1982_08
特許番号
US04345016

関連ノート

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