HCID 178420439、化合物 → HCID 178527984、化合物
反応式
C([S:8][C:9]1[N:10]=[N:11][N:12]([CH2:14][C:15]2[NH:19][N:18]=[N:17][N:16]=2)[N:13]=1)C1C=CC=CC=1>[Hg].CN(C=O)C>[NH:16]1[C:15]([CH2:14][N:12]2[N:11]=[N:10][C:9]([SH:8])=[N:13]2)=[N:19][N:18]=[N:17]1参加物
4
実験手順
5-Benzylthio-2-(1H-tetrazole-5-ylmethyl)-2H-tetrazole, 175 mg., prepared as described above under part C, was dissolved in 40 ml. of distilled DMF and reduced at the mercury pool cathode (14 cm2Hg pool) with a platinium wire anode. The electrodes were separated by a glass frit. The electrolyte was tetraethylammonium perchlorate, 0.1 M in the DMF solution of the substrate. The electrolysis was carried out at -2.7 to -2.85 volts for 500 seconds at -2.80 v. for about 630 seconds.
後処理
- custom, prepared
- dissolutionwas dissolved in 40 ml
- customThe electrodes were separated by a glass frit
- waitfor about 630 seconds
出典と根拠
- ORDレコード
- ord-dbfda54e117c45e19392383469be9c01
- 出典データセット
- uspto-grants-1982_08
- 特許番号
- US04346076
反応ノート
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