化工社化工社 化学情報印刷レポート · 研究参考用
Water → 4'-(2-Cyanoethylsulfonyl)acetanilide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Water | HCID 962 | — |
| 反応物 | Acrylonitrile | HCID 7855 | — |
| 反応物 | 4-(Acetylamino)benzenesulfinic acid | HCID 412150 | — |
| 溶媒 | Acetic Acid | HCID 176 | — |
| 生成物 | 4'-(2-Cyanoethylsulfonyl)acetanilide | HCID 3239094 | 68% |
反応手順
A solution of 19.9 g (0.1 mol) of p-acetamidobenzenesulfinic acid (Organic Synthesis, Coll. Vol. I, page 7), 100 ml of water, 40 ml of acetic acid and 6.6 ml (0.1 mole) of acrylonitrile was heated on a steam bath for 2 hours. The resulting slurry was cooled to room temperature, filtered, washed with water and air dried to give 17.1 g (68 percent) of white solid.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04346161 |
| 出典データセット | uspto-grants-1982_08 |
| ORD ID | ord-d1d7a3698d964e64a37125f599761ebc |
| 出典メモ | uspto-grants-1982_08 |