化工社化工社 化学情報印刷レポート · 研究参考用
Dibenzylidene acetone → Tris(dibenzylideneacetone) palladium
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Dibenzylidene acetone | HCID 95417 | — |
| 反応物 | 1,5-Diphenylpenta-1,4-dien-3-one;palladium | HCID 154270 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | Tris(dibenzylideneacetone) palladium | HCID 44556509 | — |
反応手順
Bis-(dibenzylidene acetone) palladium (0.10 g; 0.17 mmole) was dissolved in methylene chloride (100 ml), and the solution filtered on a millepore filter to remove elemental palladium. Dibenzylidene acetone (0.51 mmole) was added to the solution, and the solution was stirred for 24 hours at ambient temperature. The solution was then evaporated to yield purple crystals of the tris-(dibenzylidene acetone) palladium product.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04347232 |
| 出典データセット | uspto-grants-1982_08 |
| ORD ID | ord-bb8737df082d429b8775616499e8e7ff |
| 出典メモ | uspto-grants-1982_08 |