Benzene, 1-bromo-3-iodo- → 3-(3-Bromophenyl)phenanthrene

HRID 68507

反応式

HRID 68507 の反応式
BrC1C=CC([C:8]2[CH:21]=[CH:20][C:19]3[C:18]4[C:13](=[CH:14][CH:15]=[CH:16][CH:17]=4)[CH:12]=[CH:11][C:10]=3[CH:9]=2)=CC=1.C1(B(O)O)C2C=CC3C(=CC=CC=3)C=2C=CC=1.[Br:39][C:40]1[CH:41]=[C:42](I)[CH:43]=[CH:44][CH:45]=1>>[Br:39][C:40]1[CH:45]=[C:44]([C:10]2[CH:11]=[CH:12][C:21]3[CH:20]=[CH:19][C:18]4[C:17]([C:8]=3[CH:9]=2)=[CH:16][CH:15]=[CH:14][CH:13]=4)[CH:43]=[CH:42][CH:41]=1

参加物

4

反応物 3

HCID 11561Benzene, 1-bromo-3-iodo-HCID 10082252Phenanthreneboronic acidHCID 581942352-(4-Bromophenyl)phenanthrene

生成物 1

HCID 581941693-(3-Bromophenyl)phenanthrene

実験手順

Synthesis was performed in the same manner as in the synthesis of 2-(4-bromophenyl)phenanthrene except that: phenanthrene-1-boronic acid was used instead of phenanthrene-2-boronic acid; and 3-bromoiodobenzene was used instead of 4-bromoiodobenzene.

後処理

  1. customSynthesis

出典と根拠

ORDレコード
ord-c7b9cc7e0b7641138220821dcffe5a89
出典データセット
uspto-grants-2014_09
特許番号
US08822041B2

関連ノート

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