化工社化工社 化学情報印刷レポート · 研究参考用
Methylhydrazine → (E)-(2,4,6-trifluorophenyl)methylidenehydrazine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methylhydrazine | HCID 6061 | — |
| 反応物 | 2,4,6-Trifluorobenzaldehyde | HCID 521845 | — |
| 溶媒 | Diethyl Ether | HCID 3283 | — |
| 生成物 | (E)-(2,4,6-trifluorophenyl)methylidenehydrazine | HCID 57917272 | — |
反応手順
2,4,6-Trifluoro-benzaldehyde (x) (4.5 g, 27.3 mmol) was dissolved in Et2O, methylhydrazine was added (1.43 mL, 27.3 mmol) and the RM was stirred overnight. The solvent was evaporated and the solid residue was suspended in a mixture of pentane and EtOAc to afford after filtration the title compound as a bright yellow crystalline solid (tR 4.95 min (conditions 3), MH+=198.1).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08822468B2 |
| 出典データセット | uspto-grants-2014_09 |
| ORD ID | ord-cd338e979c4d47d48408e78b4dc0922f |
| 出典メモ | uspto-grants-2014_09 |