Dimethyl Sulfoxide → 1-[3-(3-Methylbut-2-enyloxy)-5,6,7,8-tetrahydro-5,5,8,8-tetramethylnaphthalen-2-yl]ethanone

反応式

[Br:19][CH2:20][CH:21]=[C:22]([CH3:23])[CH3:24].[CH3:25][S:26]([CH3:27])=[O:28].[OH:1][c:2]1[c:3]([C:16]([CH3:17])=[O:18])[cH:4][c:5]2[c:10]([cH:11]1)[C:9]([CH3:12])([CH3:13])[CH2:8][CH2:7][C:6]2([CH3:14])[CH3:15]>>[O:1]([c:2]1[c:3]([C:16]([CH3:17])=[O:18])[cH:4][c:5]2[c:10]([cH:11]1)[C:9]([CH3:12])([CH3:13])[CH2:8][CH2:7][C:6]2([CH3:14])[CH3:15])[CH2:20][CH:21]=[C:22]([CH3:23])[CH3:24]

参加物

反応物 3

HCID 679Dimethyl Sulfoxide

HCID 700922-Butene, 1-bromo-3-methyl-

HCID 2266995,6,7,8-Tetrahydro-3-hydroxy-5,5,8,8-tetramethyl-2-naphthyl methyl ketone

生成物 1

HCID 186149261-[3-(3-Methylbut-2-enyloxy)-5,6,7,8-tetrahydro-5,5,8,8-tetramethylnaphthalen-2-yl]ethanone

出典と根拠

ORDレコード: ord-62fa80bb343141938850e109df6aaf49
出典データセット: Training data from https://doi.org/10.1039/C8SC04228D (3/10)
DOI: 10.1039/C8SC04228D

反応ノート

読み込み中…