1-Bromodecane → (4-Decyloxyphenyl)phenyliodonium tosylate

HRID 703193ノート

反応式

HRID 703193 の反応式
F[Sb-](F)(F)(F)(F)F.[CH2:8]([O:18][C:19]1[CH:24]=[CH:23][C:22]([I+:25][C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)=[CH:21][CH:20]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].BrCCCCCCCCCC.C1(OCCCCCCCCCC)C=CC=CC=1.[S:60]([C:72]1[CH:78]=[CH:77][C:75]([CH3:76])=[CH:74][CH:73]=1)([O:63][IH](C1C=CC=CC=1)=O)(=[O:62])=[O:61]>ClCCl.C(O)(=O)C>[S:60]([C:72]1[CH:78]=[CH:77][C:75]([CH3:76])=[CH:74][CH:73]=1)([O-:63])(=[O:62])=[O:61].[CH2:8]([O:18][C:19]1[CH:24]=[CH:23][C:22]([I+:25][C:26]2[CH:31]=[CH:30][CH:29]=[CH:28][CH:27]=2)=[CH:21][CH:20]=1)[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17]

参加物

7

反応物 4

HCID 81731-BromodecaneHCID 520713Decyloxybenzene2 回HCID 16687828(4-Decyloxyphenyl)phenyliodonium hexafluoroantimonateHCID 178427798HCID 178427798、化合物

生成物 1

HCID 86743519(4-Decyloxyphenyl)phenyliodonium tosylate収率 67.5%

試薬・触媒・溶媒 2

HCID 176Acetic Acid溶媒HCID 6344Dichloromethane溶媒

実験手順

The procedure of Example 1 was repeated to prepare (4-decyloxyphenyl)phenyliodonium hexafluoroantimonate. 1-bromodecane was used and the yield of decyl phenyl ether was 98.9%. In accordance with Example 1, 196 grams (0.5 mol) of phenyliodoso tosylate, 117 grams (0.5 mol) of the decyl phenyl ether, 50 ml of acetic acid and 200 ml of dichloromethane were stirred at 40° C. for 2 hours. The reaction mixture was filtered and a solution triturated with ether. The crystallized product was isolated by suction filtration and washed with ether and then dried under vacuum. There was obtained, 205.3 grams (67.5% yield of (4-decyloxyphenyl)phenyliodonium tosylate.

後処理

  1. filtrationThe reaction mixture was filtered
  2. customa solution triturated with ether
  3. customThe crystallized product was isolated by suction filtration
  4. washwashed with ether
  5. customdried under vacuum
  6. customThere was obtained

出典と根拠

ORDレコード
ord-b584eb2ed42c49fe8c52b4e5c3528138
出典データセット
uspto-grants-1991_01
特許番号
US04981881

反応ノート

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