1-[4-(t-Butyldimethylsilyl)oxy-2,6,6-Trimethylcyclohex-1-enyl]Oct-1-en-3-one → 1-(2,4-Dihydroxy-2,6,6-Trimethylcyclohexyl)Oct-1-en-3-ol

反応式

[Si]([O:8][CH:9]1[CH2:14][C:13]([CH3:16])([CH3:15])[C:12]([CH:17]=[CH:18][C:19](=[O:25])[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24])=[C:11]([CH3:26])[CH2:10]1)(C(C)(C)C)(C)C.[OH:27]C1(C)CC(O)CC(C)(C)C1C=CC(O)C>>[OH:27][C:11]1([CH3:26])[CH2:10][CH:9]([OH:8])[CH2:14][C:13]([CH3:16])([CH3:15])[CH:12]1[CH:17]=[CH:18][CH:19]([OH:25])[CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]

参加物

反応物 2

HCID 540453681-[4-(t-Butyldimethylsilyl)oxy-2,6,6-Trimethylcyclohex-1-enyl]Oct-1-en-3-one

HCID 541764534-(2,4-Dihydroxy-2,6,6-trimethylcyclohexyl)but-3-en-2-ol

生成物 1

HCID 540279911-(2,4-Dihydroxy-2,6,6-Trimethylcyclohexyl)Oct-1-en-3-ol

実験手順

The entitled compound was prepared from 1-[4-(t-butyldimethylsilyl)oxy-2,6,6-trimethylcyclohex-1enyl]oct-1-en-3-one in the same manner as described in Example 1-(4), (5), and (6).

出典と根拠

ORDレコード: ord-fe29ae79c6b3458d87adb54d7872914e
出典データセット: uspto-grants-1991_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04983723

反応ノート

読み込み中…