1,1-Dichlorosilacyclobutane → 1,1-Diacetamidosilacyclobutane

HRID 704072

反応式

HRID 704072 の反応式
C[Si]([CH2:5][C:6]([NH2:8])=[O:7])(C)C.Cl[Si:10]1(Cl)[CH2:13][CH2:12][CH2:11]1>C(Cl)Cl>[C:6]([NH:8][Si:10]1([NH:8][C:6](=[O:7])[CH3:5])[CH2:13][CH2:12][CH2:11]1)(=[O:7])[CH3:5]

参加物

4

反応物 2

HCID 753731,1-DichlorosilacyclobutaneHCID 357676Acetamide, 2-(trimethylsilyl)-

生成物 1

HCID 200755231,1-Diacetamidosilacyclobutane

試薬・触媒・溶媒 1

HCID 6344Dichloromethane溶媒

実験手順

When 1.72 g of trimethylsilylacetamide was mixed with 0.92 g of 1,1-dichlorosilacyclobutane in 5 g of methylene chloride, a white precipitate formed. The precipitate dissoved upon shaking and slowly recrystallized as white needles. There was no trimethylchlorosilane detected in the residual fluid, indicating that the expected reaction to form 1,1-diacetamidosilacyclobutane did not occur.

後処理

  1. customa white precipitate formed
  2. customslowly recrystallized as white needles
  3. customreaction

出典と根拠

ORDレコード
ord-c2cd10faa21e40fbbb19209d3ea4c1b8
出典データセット
uspto-grants-1991_01
特許番号
US04985565

関連ノート

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