Hexane → Chloramben-methyl

HRID 705455

反応式

HRID 705455 の反応式
[Cl:1][C:2]1[C:10]([NH2:11])=[CH:9][C:8]([Cl:12])=[CH:7][C:3]=1[C:4]([OH:6])=[O:5].[CH3:13]CCCCC.C[Si](C=[N+]=[N-])(C)C>CC(C)=O>[Cl:1][C:2]1[C:10]([NH2:11])=[CH:9][C:8]([Cl:12])=[CH:7][C:3]=1[C:4]([O:6][CH3:13])=[O:5]

参加物

5

反応物 3

HCID 8058HexaneHCID 8630ChlorambenHCID 167693Trimethylsilyldiazomethane

生成物 1

HCID 23714Chloramben-methyl

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

206 mg (1.0 mmol) of 2,5-Dichloro-3-aminobenzoic acid was dissolved in 4 mL of acetone. 0.7 mL (1.4 mmol) of A hexane solution of 2.0M trimethylsilyldiazomethane was added thereto and stirred at room temperature for 1.5 hours. A solvent was removed to obtain methyl 2,5-dichloro-3-aminobenzoate.

後処理

  1. customA solvent was removed

出典と根拠

ORDレコード
ord-1cfcecd5fdcd4c12abcdfff6406355ba
出典データセット
uspto-grants-2015_11
特許番号
US09174932B2

関連ノート

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