endo-Dicyclopentadiene → Dicyclopentadiene

HRID 70723

反応式

HRID 70723 の反応式
[CH2:1]1[CH:5]2[C@@H:6]3[CH:10]=[CH:9][C@H:8]([CH:4]2[CH:3]=[CH:2]1)[CH2:7]3>Cl[Ru](=CC1C=CC=CC=1)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)([P](C1CCCCC1)(C1CCCCC1)C1CCCCC1)Cl>[CH2:1]1[CH:5]2[CH:6]3[CH:10]=[CH:9][CH:8]([CH:4]2[CH:3]=[CH:2]1)[CH2:7]3

参加物

3

反応物 1

HCID 15618652endo-Dicyclopentadiene2 回

生成物 1

HCID 6492Dicyclopentadiene

試薬・触媒・溶媒 1

HCID 178479819HCID 178479819、化合物触媒

実験手順

Grubbs catalyst containing MCs (approximately 1 mg) were dispersed in neat DCPD (100 mg). The MCs were ruptured with a laser or by physical crushing. After rupturing, a gel was produced in approximately 10-30 minutes, with formation of a rubbery state, and then a solid resin over time. No gelling of DCPD was evident over two weeks with uncrushed MCs; however, the latent catalyst remained active as subsequent rupture of the MCs that had been left for five days still produced a gel in approximately 45-60 minutes. A background gelling rate of approximately 1 day was obtained with prepared particles that were not free flowing.

後処理

  1. customa gel was produced in approximately 10-30 minutes, with formation of a rubbery state
  2. customstill produced a gel in approximately 45-60 minutes
  3. customrate of approximately 1 day
  4. customwas obtained with prepared particles that

出典と根拠

ORDレコード
ord-28128eb9393442438c449ae2b9ebcc04
出典データセット
uspto-grants-2014_09
特許番号
US08822618B2

関連ノート

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