Tert-butyl (4-iodo-2-nitrophenyl)carbamate → (2-Amino-4-iodo-phenyl)-carbamic acid tert-butyl ester
反応式
[I:1][C:2]1[CH:7]=[CH:6][C:5]([NH:8][C:9](=[O:15])[O:10][C:11]([CH3:14])([CH3:13])[CH3:12])=[C:4]([N+:16]([O-])=O)[CH:3]=1>[Zn]>[NH2:16][C:4]1[CH:3]=[C:2]([I:1])[CH:7]=[CH:6][C:5]=1[NH:8][C:9](=[O:15])[O:10][C:11]([CH3:13])([CH3:12])[CH3:14]参加物
3
実験手順
The title compound was prepared from the tert-butyl 4-iodo-2-nitrophenylcarbamate (Example A3; 3 mmol) by reduction with zinc according to the general procedure B. Obtained as a yellow solid (44%), MS (EI) 335 [(M+1)+].
出典と根拠
- ORDレコード
- ord-9289f726bb2346529edd0189d64d88b5
- 出典データセット
- uspto-grants-2015_11
- 特許番号
- US09193710B2
反応ノート
読み込み中…