Methyl 4-[(tert-butoxy)carbonylamino]-3-nitrobenzoate → Methyl 3-amino-4-((tert-butoxycarbonyl)amino)benzoate
反応式
[N+:1]([C:4]1[CH:5]=[C:6]([CH:11]=[CH:12][C:13]=1[NH:14][C:15]([O:17][C:18]([CH3:21])([CH3:20])[CH3:19])=[O:16])[C:7]([O:9][CH3:10])=[O:8])([O-])=O>[Zn]>[NH2:1][C:4]1[CH:5]=[C:6]([CH:11]=[CH:12][C:13]=1[NH:14][C:15]([O:17][C:18]([CH3:21])([CH3:20])[CH3:19])=[O:16])[C:7]([O:9][CH3:10])=[O:8]参加物
3
実験手順
The title compound was prepared from the methyl 3-nitro-4-((tert-butoxycarbonyl)amino)benzoate (Example A4; 3 mmol) by reduction with zinc according to the general procedure B. Obtained as a yellow solid (71%), MS (EI) 267 [(M+1)+].
出典と根拠
- ORDレコード
- ord-db3a3384843c452ab6abcce6e2440a41
- 出典データセット
- uspto-grants-2015_11
- 特許番号
- US09193710B2
反応ノート
読み込み中…