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Water → 1,2,3,4-Tetramethylimidazolinium diethyl phosphate

HRID 72069
ノート
印刷プレビュー

反応式

HRID 72069 の反応式
[P:1]([O:9]CC)([O:6][CH2:7][CH3:8])([O:3][CH2:4][CH3:5])=[O:2].COC(=O)[O-].[CH3:17][NH+:18]1[CH2:22][CH:21]([CH3:23])[N:20]([CH3:24])[CH:19]1[CH3:25].O>CO>[CH2:4]([O:3][P:1]([O-:9])([O:6][CH2:7][CH3:8])=[O:2])[CH3:5].[CH3:17][NH+:18]1[CH2:22][CH:21]([CH3:23])[N:20]([CH3:24])[CH:19]1[CH3:25]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

5

反応物 3

HCID 962WaterHCID 6535Triethyl Phosphate2 回HCID 675213621,2,3,4-Tetramethylimidazolinium methyl carbonate

生成物 1

HCID 675210061,2,3,4-Tetramethylimidazolinium diethyl phosphate

試薬・触媒・溶媒 1

HCID 887Methanol溶媒2 回

反応条件

温度
100 °C

実験手順

By adding 42 parts of triethyl phosphate (TEP: produced by Daihachi Chemical Industries Co., Ltd.) to the methanol solution of 46 parts of 1,2,3,4-tetramethylimidazolinium methyl carbonate salt obtained in Production Example 1, followed by addition of 5.4 parts of water and stirring at 100° C. for 20 hours, triethyl phosphate was hydrolyzed and a salt exchange reaction was carried out to obtain a methanol solution of 1,2,3,4-tetramethylimidazolinium diethyl phosphate monoanion. The above-described solution was heated under reduced pressure of 1.0 kPa or less at 50° C. to distill methanol until no distillate of methanol was observed. Thereafter, the temperature was raised from 50° C. to 100° C. and heating was continued for 30 minutes to distill and remove monomethyl carbonate (HOCO2CH3), methanol, and carbon dioxide (slight amounts of methanol and carbon dioxide are formed by thermal decomposition of monomethyl carbonate. Hereinafter, these are abbreviated as by-products). Thus, 1,2,3,4-tetramethylimidazolinium diethyl phosphate monoanion, electrolyte (C-2), was obtained. The yield was 99 parts (yield based on the weight of 46 parts of 1,2,3,4-tetramethylimidazolinium methyl carbonate salt; hereinafter the same shall apply). The molecular weight of the electrolyte (C-2) was 280.

後処理

  1. customobtained in Production Example 1
  2. customa salt exchange reaction

出典と根拠

ORDレコード
ord-2ae1313bd9d44f81a5e881f8caebf5b9
出典データセット
uspto-grants-2014_09
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US08828261B2

反応ノート

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