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Methyl vinyl sulfone → 1-(2-Methanesulfonyl-ethyl)-4-(4-nitro-phenyl)-[1,4]diazepane
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methyl vinyl sulfone | HCID 19354 | — |
| 反応物 | 1-(4-Nitrophenyl)-1,4-diazepane | HCID 5055950 | — |
| 溶媒 | Methanol | HCID 887 | — |
| 生成物 | 1-(2-Methanesulfonyl-ethyl)-4-(4-nitro-phenyl)-[1,4]diazepane | HCID 68979613 | — |
反応手順
A mixture of 1-(4-Nitro-phenyl)-[1,4]diazepane (4.90 g), Methansulfonyl-ethene (2.35 g) and Methanol (50 mL) was stirred for 2 h at room temperature. The volatiles were removed in vacuo. The product with the molecular weight of 327.40 (C14H21N3O4S) was obtained in this way; MS (ESI): 328 (M+H+).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08828991B2 |
| 出典データセット | uspto-grants-2014_09 |
| ORD ID | ord-f675f3baab6544c48293dbeb4ed82bcd |
| 出典メモ | uspto-grants-2014_09 |