N,N,N'-trimethyl-N'-(4-nitrophenyl)-1,2-ethanediamine → N-(2-Dimethylaminoethyl)-N-methylbenzene-1,4-diamine

反応式

[CH3:1][N:2]([CH3:16])[CH2:3][CH2:4][N:5]([CH3:15])[C:6]1[CH:11]=[CH:10][C:9]([N+:12]([O-])=O)=[CH:8][CH:7]=1>[Zn]>[CH3:1][N:2]([CH3:16])[CH2:3][CH2:4][N:5]([CH3:15])[C:6]1[CH:11]=[CH:10][C:9]([NH2:12])=[CH:8][CH:7]=1

参加物

実験手順

The compound was prepared by zinc dust reduction of N,N,N′-trimethyl-N′-(4-nitrophenyl)ethane-1,2-diamine in analogy to the method in example 3. The product with the molecular weight of 193.29 (C11H19N3); MS (ESI): 194 ([M+H]+), was obtained in this way.

後処理

customMS (ESI): 194 ([M+H]+), was obtained in this way

出典と根拠

ORDレコード: ord-31bccd887b124b24bf2f233545e19fbf
出典データセット: uspto-grants-2006_11
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07141561B2

反応ノート

読み込み中…

参加物

反応物 1

HCID 21873305N,N,N'-trimethyl-N'-(4-nitrophenyl)-1,2-ethanediamine

生成物 1

HCID 21873395N-(2-Dimethylaminoethyl)-N-methylbenzene-1,4-diamine

試薬・触媒・溶媒 1

HCID 23994Zinc触媒

実験手順

後処理

customMS (ESI): 194 ([M+H]+), was obtained in this way

出典と根拠

ORDレコード: ord-31bccd887b124b24bf2f233545e19fbf
出典データセット: uspto-grants-2006_11
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US07141561B2

反応ノート

読み込み中…