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Methane → 1,1,1-Triphenyl-4-acetoxy-1-sila-2-butene
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Methane | HCID 297 | — |
| 反応物 | 1,3-Butadienyl acetate | HCID 15195 | — |
| 反応物 | Triphenylsilane | HCID 69922 | — |
| 溶媒 | Toluene | HCID 1140 | — |
| 生成物 | 1,1,1-Triphenyl-4-acetoxy-1-sila-2-butene | HCID 53800522 | — |
反応手順
A solution of 1-acetoxy-1,3-butadiene (0.1 mol), triphenylsilane (0.1 mol), and Rh2Cl2 (CO)4 (194.5 mg, 0.625 mol) in 100 mL of toluene was stirred at room temperature under argon for 3 days. The reaction mixture is treated with decolorizing charcoal, and the mixture boiled briefly. After cooling, the reaction mixture is filtered through Celite. Concentration of the solution will afford the title compound.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05705621 |
| 出典データセット | uspto-grants-1998_01 |
| ORD ID | ord-b5ee4f6de64b43358c2bd1410e582d1c |
| 出典メモ | uspto-grants-1998_01 |