化工社化工社 化学情報印刷レポート · 研究参考用
Nitrite → N-Nitrosodiphenylamine
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Nitrite | HCID 946 | — |
| 反応物 | Diphenylamine | HCID 11487 | — |
| 生成物 | N-Nitrosodiphenylamine | HCID 6838 | — |
反応手順
diphenylamine method, where diphenylamine as raw material is nitrosated using a nitrite in an organic solvent to produce N-nitrosodiphenylamine, which is rearranged to 4-nitrosodiphenylamine hydrochloride under the action of anhydrous hydrogen chloride, and then, 4-nitrosodiphenylamine hydrochloride is neutralized with a base to give 4-nitrosodiphenylamine which is finally reduced to 4-aminodiphenylamine by sodium sulfide.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US07084302B2 |
| 出典データセット | uspto-grants-2006_08 |
| ORD ID | ord-e70b01ed6e6a4bcc904277bc74d3110e |
| 出典メモ | uspto-grants-2006_08 |