化工社化工社 化学情報印刷レポート · 研究参考用
1-Phenethylamine, (+)- → (R)-N-tert-butyl-3,3-dimethyl-2-(1-phenylethylimino)-butyramide
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Phenethylamine, (+)- | HCID 643189 | — |
| 反応物 | N-tert-Butyl-3,3-dimethyl-2-oxobutanamide | HCID 13355144 | — |
| 生成物 | (R)-N-tert-butyl-3,3-dimethyl-2-(1-phenylethylimino)-butyramide | HCID 54448076 | 58.2% |
反応手順
The procedure described under l) was carried out using 7.5 g of N-tert-butyl-3,3-dimethyl-2-oxo-butyramide and 15 g of (R)-1-phenylethylamine. There were isolated 6.8 g (58%) of (R)-N-tert-butyl-3,3-dimethyl-2-(1-phenylethylimino)-butyramide of boiling point 120° at 0.2 mbar. [α]=+40.9 (c=1.0, CHCl3).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05710322 |
| 出典データセット | uspto-grants-1998_01 |
| ORD ID | ord-226a520cff7e4dce9cd8b645360985ee |
| 出典メモ | uspto-grants-1998_01 |