Isodecanol → Hexanoic acid, 3,5,5-trimethyl-, isodecyl ester

反応式

[CH3:1][CH:2]([CH2:7][C:8]([CH3:11])([CH3:10])[CH3:9])[CH2:3][C:4]([OH:6])=[O:5].[CH2:12](O)[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH:19]([CH3:21])[CH3:20]>>[CH2:12]([O:5][C:4](=[O:6])[CH2:3][CH:2]([CH3:1])[CH2:7][C:8]([CH3:10])([CH3:9])[CH3:11])[CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH:19]([CH3:21])[CH3:20]

参加物

反応物 2

HCID 32898Isodecanol

HCID 909603,5,5-Trimethylhexanoic acid

生成物 1

HCID 100992Hexanoic acid, 3,5,5-trimethyl-, isodecyl ester

実験手順

The preparation from 3,5,5-trimethylhexanoic acid and isodecyl alcohol (mixture of methyl branched primary decanols from Hoechst) was analogous to Example 3; colorless liquid of medium viscosity; B.P. (1.3 mbar)=148°-154° C.

後処理

custom(1.3 mbar)=148°-154° C.

出典と根拠

ORDレコード: ord-72ed2d4258124037a19841298be1ea94
出典データセット: uspto-grants-1998_01
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US05711939

反応ノート

読み込み中…