N-methyl-N-phenyl-hydrazine → 5-(3,6-Dihydro-6-methyl-2-oxo-2H-1,3,4-thiadiazin-5-yl)-1H-indole-2,3-dione 3-(methylphenylhydrazone)

HRID 728783ノート

反応式

HRID 728783 の反応式
[CH3:1][CH:2]1[S:7][C:6](=[O:8])[NH:5][N:4]=[C:3]1[C:9]1[CH:10]=[C:11]2[C:15](=[CH:16][CH:17]=1)[NH:14][C:13](=[O:18])[C:12]2=[N:19]C1C=CC=CC=1.[CH3:26][N:27]([C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)N>>[CH3:26][N:27]([C:29]1[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1)[N:19]=[C:12]1[C:11]2[C:15](=[CH:16][CH:17]=[C:9]([C:3]3[CH:2]([CH3:1])[S:7][C:6](=[O:8])[NH:5][N:4]=3)[CH:10]=2)[NH:14][C:13]1=[O:18]

参加物

3

反応物 2

HCID 36299N-methyl-N-phenyl-hydrazineHCID 1357781391,3-dihydro-5-(3,6-dihydro-6-methyl-2-oxo-2H-1,3,4-thiadiazin-5-yl)-3-phenylimino-2H-indol-2-one

生成物 1

HCID 1363411915-(3,6-Dihydro-6-methyl-2-oxo-2H-1,3,4-thiadiazin-5-yl)-1H-indole-2,3-dione 3-(methylphenylhydrazone)収率 47%

実験手順

Starting from 1,3-dihydro-5-(3,6-dihydro-6-methyl-2-oxo -2H-1,3,4-thiadiazin-5-yl)-3-phenylimino-2H-indol-2-one, and 1-methyl 1-phenylhydrazine and following the method described in Example 21, the desired compound was obtained.

出典と根拠

ORDレコード
ord-f416d5cc454c454a9daa9c035655eaae
出典データセット
uspto-grants-1991_09
特許番号
US05051417

反応ノート

読み込み中…