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(-)-Asparagine → Aspartate asparagine

HRID 736016
ノート
印刷プレビュー

反応式

HRID 736016 の反応式
[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([O-:6])=[O:5].[NH4+].[NH4+].[NH2:12][C@H:13]([C:18]([OH:20])=[O:19])[CH2:14][C:15](=[O:17])[NH2:16].[OH-].[NH4+]>O>[NH2:1][C@H:2]([C:7]([O-:9])=[O:8])[CH2:3][C:4]([O-:6])=[O:5].[NH2:12][C@H:13]([C:18]([OH:20])=[O:19])[CH2:14][C:15](=[O:17])[NH2:16]
参加物反応条件実験手順後処理出典と根拠反応ノート

参加物

5

反応物 3

HCID 6267(-)-AsparagineHCID 14923Ammonium Hydroxide3 回HCID 86590683Ammonium Aspartate

生成物 1

HCID 86612007Aspartate asparagine

試薬・触媒・溶媒 1

HCID 962Water溶媒2 回

反応条件

温度
3 °C

実験手順

The reaction conditions and procedures of Example 9, for production of copolymers of ammonium aspartate and asparagine from polysuccinimides, were followed with the additional inclusion of crosslinker molecules along with the ammonium hydroxide. Accordingly, a sample of polysuccinimide, preferably comprised of high Mw, linear molecules (e.g. from Example 3), was slurried in water at 20 g in 100 ml water. The slurry was cooled to 2-4° C., by use of a refrigerated recirculating bath and a water-jacketed glass vessel, and precooled, concentrated ammonium hydroxide (twofold excess) was added, keeping the temperature at 2-4° C. The crosslinker, in a cooled solution of ammonium hydroxide, was added to the precooled slurry of polysuccinimide, and the reaction mixture was then stirred for 2 to 4 hours until a complete solution was formed. Water was removed at 80° C. in a forced-air oven, producing a dried product of lightly crosslinked aspartate/asparagine copolymer.

後処理

  1. customThe reaction conditions and procedures of Example 9
  2. customat 2-4° C
  3. customwas formed
  4. customWater was removed at 80° C. in a forced-air oven

出典と根拠

ORDレコード
ord-95e7b14ed6c9480a81cd61741e70ec06
出典データセット
uspto-grants-2009_09
DOI
10.6084/m9.figshare.5104873.v1
特許番号
US07595002B2

反応ノート

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