反応式
[NH2:1][CH2:2][C:3]1([CH3:12])[CH2:8][C:7]([CH3:10])([CH3:9])[CH2:6][CH:5]([NH2:11])[CH2:4]1.C(C1(C)CC(C)(C)CC(=O)C1)#N.N>>[NH2:1][CH2:2][C:3]1([CH3:12])[CH2:8][C:7]([CH3:9])([CH3:10])[CH2:6][CH:5]([NH2:11])[CH2:4]1.[C:2]([C:3]1([CH3:12])[CH2:8][C:7]([CH3:9])([CH3:10])[CH2:6][CH:5]([NH2:11])[CH2:4]1)#[N:1]参加物
実験手順
3-Aminomethyl-3,5,5-trimethylcyclohexylamine (i.e., isophoronediamine, abbreviated as IPDA) is used as a starting material for preparing substances such as 3-isocyanatomethylene-3,5,5-trimethylcyclohexyl isocyanate (i.e., isophorone diisocyanate, abbreviated as IPDI) or polyamides, and also used as a curing agent for epoxy resins. 3-Aminomethyl-3,5,5-trimethylcyclohexylamine is prepared, on an industrial scale, by reacting 3-cyano-3,5,5-trimethylcyclohexanone (i.e., isophoronenitrile, abbreviated as IPN) with ammonia to form 3-cyano-3,5,5-trimethylcyclohexylamine (i.e., isophoronenitrilimine, abbreviated as IPNI), followed by a reductive amination reaction of IPNI with hydrogen in the presence of ammonia in a catalytic way. The above reaction processes are as follows:
出典と根拠
- ORDレコード
- ord-8e8900f9242844e7b85115ed9dba1080
- 出典データセット
- uspto-grants-2014_09
- 特許番号
- US08829245B2
関連ノート
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