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Glycolic Acid → Formate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | Glycolic Acid | HCID 757 | — |
| 反応物 | alpha-AMINO-3-HYDROXY-5-METHYL-4-ISOXAZOLEPROPIONIC ACID | HCID 1221 | — |
| 反応物 | Isobutyric Acid | HCID 6590 | — |
| 反応物 | Hydroxyacetate | HCID 5460308 | — |
| 生成物 | Formate | HCID 283 | — |
| 生成物 | Oxalate | HCID 71081 | — |
| 生成物 | Npc324351 | HCID 3614358 | — |
反応手順
The procedure described in Example 1 was repeated using an aqueous solution containing glycolic acid (0.500M), AMPA (0.500M), FMN (0.01 mM), isobutyric acid (HPLC internal standard, 0.100M), spinach glycolate oxidase (1.0 IU/mL), and soluble Aspergillus niger catalase (14,000 IU/mL) at pH 8.5 and at 5° C. After 21 h, the HPLC yields of glyoxylate, formate, and oxalate were 85.2%, 1.5%, and 3.3%, respectively, and 5.5% glycolate remained. The remaining activities of glycolate oxidase and catalase were 49% and 93%, respectively, of their initial values.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US05559020 |
| 出典データセット | uspto-grants-1996_09 |
| ORD ID | ord-6a4dcf6fef69435195dfaa2003acc3f7 |
| 出典メモ | uspto-grants-1996_09 |