化工社化工社 化学情報印刷レポート · 研究参考用
m-Chloroperbenzoic acid → 5-Bromo-2-methylpyridin-1-ium-1-olate
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | m-Chloroperbenzoic acid | HCID 70297 | — |
| 反応物 | 5-Bromo-2-methylpyridine | HCID 1201020 | — |
| 溶媒 | Dichloromethane | HCID 6344 | — |
| 生成物 | 5-Bromo-2-methylpyridin-1-ium-1-olate | HCID 817164 | — |
反応手順
39 g (0.16 mol) 3-chloroperbenzoic acid in 450 mL DCM (dried on sodium sulphate) were added dropwise within 2 h to 25 g (0.15 mol) 5-bromo-2-methylpyridine in 50 mL DCM. Then the reaction mixture was stirred for 20 h at RT and extracted with 15% potassium carbonate solution. The organic phase was dried on sodium sulphate and evaporated down.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US08829006B2 |
| 出典データセット | uspto-grants-2014_09 |
| ORD ID | ord-1b569edf3019470e82be611f0b8f9530 |
| 出典メモ | uspto-grants-2014_09 |