3-Methylbicyclo(2.2.1)heptane-2-methanol → Santene
反応式
[O-2].[O-2].[O-2].[Al+3].[Al+3].O[CH2:7][CH:8]1[CH:13]([CH3:14])[CH:12]2[CH2:15][CH:9]1[CH2:10][CH2:11]2.C=C1C(C)C2CC1CC2>>[CH3:7][C:8]1[CH:9]2[CH2:15][CH:12]([C:13]=1[CH3:14])[CH2:11][CH2:10]2参加物
4
実験手順
Into an atmospheric reaction tube of the flow type made of quartz and having an outer diameter of 20 mm and a length of 500 mm, 20 g of γ-alumina (manufactured by NIKKI CHEMICAL Co., Ltd.; “N612”) was placed. The dehydration was conducted at a reaction temperature of 285° C. and a weight hourly space velocity (WHSV) of 1.1 hr−1, and 490 g of a dehydration product of 2-hydroxymethyl-3-methylbicyclo[2.2.1]heptane containing 2-methylene-3-methylbicyclo[2.2.1]heptane and 2,3-dimethyl-bicyclo[2.2.1]hept-2-ene was obtained.
後処理
- customwas conducted at a reaction temperature of 285° C.
出典と根拠
- ORDレコード
- ord-199fc93968944b5a90cbda6a5abfa8f7
- 出典データセット
- uspto-grants-2008_07
- 特許番号
- US07402715B2
反応ノート
読み込み中…