関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Acetic Acid | HCID 176 | — |
| 反応物 | Nitromethane | HCID 6375 | — |
| 反応物 | Benzaldehyde, 4-(phenylmethoxy)- | HCID 78109 | — |
| 反応物 | Ammonium Acetate | HCID 517165 | — |
| 溶媒 | Water | HCID 962 | — |
| 生成物 | (E)-1-(Benzyloxy)-4-(2-nitrovinyl)benzene | HCID 5702926 | 97.9% |
反応手順
To a mixture of 4-benzyloxy benzaldehyde (50 g, 0.24 mol) and acetic acid (200 mL) were added nitromethane (64 mL, 1.2 mol) and ammonium acetate (36 g, 0.47 mol), which was stirred for 90 minutes at 100° C. The reaction mixture was cooled to room temperature, and water (1 L) was added at the same temperature. The deposited solids were filtered to obtain the title compound (60 g).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US08841327B2 |
|---|
| 出典データセット | uspto-grants-2014_09 |
|---|
| ORD ID | ord-4245e0c393014aae9eda696d8b07c9f8 |
|---|
| 出典メモ | uspto-grants-2014_09 |
|---|
