Ethanol → (14S,15S)-5-methoxy-15-methyltetracyclo[8.7.0.0(2),7.0(1)(1),(1)5]heptadeca-2,4,6,12-tetraen-14-ol

HRID 817639

反応式

[BH4-:15].[CH3:41][CH2:42][OH:43].[Na+:16].[O:17]1[CH:18]2[CH:19]1[C:20]1([CH3:21])[CH:22]([CH2:23]2)[CH:24]2[CH2:25][CH2:26][c:27]3[cH:28][c:29]([O:36][CH3:37])[cH:30][cH:31][c:32]3[CH:33]2[CH2:34][CH2:35]1.[OH2:40].[OH:38][OH:39].[c:1]1([SeH-:2]([c:3]2[cH:4][cH:5][cH:6][cH:7][cH:8]2)=[Se:9])[cH:10][cH:11][cH:12][cH:13][cH:14]1>>[OH:17][CH:19]1[CH:18]=[CH:23][CH:22]2[C:20]1([CH3:21])[CH2:35][CH2:34][CH:33]1[CH:24]2[CH2:25][CH2:26][c:27]2[cH:28][c:29]([O:36][CH3:37])[cH:30][cH:31][c:32]21