Ammonium Hydroxide → 2-chloro-3,5-dinitrobenzamide

反応式

[Cl:1][C:2]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][C:8]([N+:14]([O-:16])=[O:15])=[CH:7][C:3]=1[C:4](Cl)=[O:5].[OH-].[NH4+:18]>>[Cl:1][C:2]1[C:10]([N+:11]([O-:13])=[O:12])=[CH:9][C:8]([N+:14]([O-:16])=[O:15])=[CH:7][C:3]=1[C:4]([NH2:18])=[O:5]

参加物

反応物 2

HCID 14923Ammonium Hydroxide

HCID 12897330HCID 12897330、化合物

生成物 1

HCID 2356272-chloro-3,5-dinitrobenzamide

実験手順

A mixture of 37.0 gm. (0.14 mole) of 2-chloro-3,5-dinitrobenzoyl chloride and 100 ml. of concentrated ammonium hydroxide is placed in a mortar, ground for ten minutes and allowed to stand for one hour. The yellow precipitate is removed by filtration and washed with water. There is obtained 32.3 gm. (94%) of material melting at 181°-3°.

後処理

additionA mixture of 37.0 gm
customThe yellow precipitate is removed by filtration
washwashed with water
customThere is obtained 32.3 gm

出典と根拠

ORDレコード: ord-74950fa737ec4e298309b5bc9455907c
出典データセット: uspto-grants-1978_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04095028

反応ノート

読み込み中…

参加物