化工社化工社 化学情報印刷レポート · 研究参考用
1-Acetylcyclopentene → 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one
関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|---|---|---|
| 反応物 | 1-Acetylcyclopentene | HCID 192925 | — |
| 反応物 | 3,4-Dihydro-6,7-dimethoxyisoquinoline hydrochloride | HCID 2724664 | — |
| 反応物 | 3,4-Dihydroisoquinoline--hydrogen chloride (1/1) | HCID 20463855 | — |
| 溶媒 | Acetone | HCID 180 | — |
| 生成物 | 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one | HCID 12774492 | — |
反応手順
When in Example 32 appropriate amounts of 3,4-dihydro-6,7-dimethoxyisoquinoline hydrochloride and 1-chylohexen-1-yl methyl ketone respectively are substituted for 3,4-dihydroisoquinoline hydrochloride and 1-cyclopenten-1-yl methyl ketone, 2,3,4,4a,6,7,11b,12,13,13a-decahydro-9,10-dimethoxy-1H-dibenzo[a,f]quinolizin-13-one is obtained M.P. 129°-141° C.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 特許番号 | US04096147 |
| 出典データセット | uspto-grants-1978_06 |
| ORD ID | ord-93740712527c4945a4bce8294a5728ce |
| 出典メモ | uspto-grants-1978_06 |