Boron trifluoride → Dilauryl Ether

反応式

[CH2:1]1[O:3][CH:2]1[CH2:4][Cl:5].[CH2:6]([OH:18])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].B(F)(F)F>>[CH2:6]([O:18][CH2:1][CH2:2][CH2:4][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17].[CH2:4]([Cl:5])/[CH:2]=[CH:1]\[OH:3]

参加物

反応物 3

HCID 6356Boron trifluoride

HCID 7835Epichlorohydrin

HCID 81931-Dodecanol

生成物 2

HCID 20667Dilauryl Ether

HCID 15676292(Z)-3-chloroprop-1-en-1-ol

実験手順

185 g of glycerol epichlorhydrin are reacted with 1 mole, i.e., 186 g of dodecanol at 75°-80° C in the presence of 1.5 ml of an acetic acid complex containing 36% BF3. Dodecyl ether of polyepichlorohydrin having the following formula is obtained:

出典と根拠

ORDレコード: ord-2c8be6aae2d641cb8578068b91f02ba0
出典データセット: uspto-grants-1978_06
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04096332

反応ノート

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