Potassium Hydroxide → HCID 12474700、化合物

HRID 840084ノート

反応式

HRID 840084 の反応式
[CH2:1]([C:9]1[CH:10]([C:12]([O:14]CC)=[O:13])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[OH-].[K+]>CCOCC>[CH2:1]([C:9]1[CH:10]([C:12]([OH:14])=[O:13])[CH:11]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8]

参加物

4

反応物 2

HCID 14797Potassium HydroxideHCID 22621698Ethyl 2-octylcycloprop-2-ene-1-carboxylate

生成物 1

HCID 12474700HCID 12474700、化合物収率 81.5%

試薬・触媒・溶媒 1

HCID 3283Diethyl Ether溶媒

実験手順

Ethyl 2-octylcycloprop-2-ene-1-carboxylate (1.12 g, 5 mmol) and 100 ml of 0.2 N potassium hydroxide were stirred at room temperature for one week. Ether was added and the phases were separated. The aqueous phase was acidified and extracted with methylene chloride. The organic phase was dried over magnesium sulfate and stripped to give 0.8 g of 2-octylcycloprop-2-ene-1-carboxylic acid.

後処理

  1. customthe phases were separated
  2. extractionextracted with methylene chloride
  3. dry with materialThe organic phase was dried over magnesium sulfate

出典と根拠

ORDレコード
ord-cf19c3b1ee5b4fdeb74266067d37b03a
出典データセット
uspto-grants-2002_04
特許番号
US06365549B2

反応ノート

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