3-amino-6,7,8,9-tetrahydro-5H-benzo[7]annulen-5-one → Methyl 6-methyl-6,7-dihydro-5H-benzocycloheptene-8-carboxylate
反応式
N[C:2]1C=CC2CCCCC(=O)C=2C=1.[CH3:14][S:15][C:16]1[CH:17]=[CH:18][C:19]2[CH2:25][CH2:24][CH2:23][C:22]([C:26]([O:28][CH3:29])=[O:27])=[CH:21][C:20]=2[CH:30]=1.CSC1C=CC2CCCCC(=O)C=2C=1>>[CH3:14][S:15][C:16]1[CH:17]=[CH:18][C:19]2[CH2:25][CH2:24][CH2:23][C:22]([C:26]([O:28][CH3:29])=[O:27])=[CH:21][C:20]=2[CH:30]=1.[CH3:2][CH:24]1[CH2:23][C:22]([C:26]([O:28][CH3:29])=[O:27])=[CH:21][C:20]2[CH:30]=[CH:16][CH:17]=[CH:18][C:19]=2[CH2:25]1参加物
5
反応物 3
生成物 2
実験手順
Methyl 2-methylthio-6,7-dihydro-5H-benzocycloheptene-8-carboxylate was synthesized by carrying out reactions according to the methods described in Reference Example 1, (a) to (c), except for using the 3-methylthio-6,7,8,9-tetrahydro-5H-benzocyclohepten-5-one obtained in the above item (b).
出典と根拠
- ORDレコード
- ord-c986fc94259648ca83bc5cfcf0a36a83
- 出典データセット
- uspto-grants-2002_04
- 特許番号
- US06369110B1
反応ノート
読み込み中…