Hydrochloric Acid → N-Dodecanoylacrylamide

HRID 841107

反応式

HRID 841107 の反応式
[C:1](Cl)(=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].[C:15]([NH2:19])(=[O:18])[CH:16]=[CH2:17].[Cl-].[Al+3].[Cl-].[Cl-].Cl.C(NC(=O)C=C)CCCCCCCCCCCCCCC>CC(C)=O>[C:1]([NH:19][C:15](=[O:18])[CH:16]=[CH2:17])(=[O:13])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

参加物

7

反応物 5

HCID 313Hydrochloric AcidHCID 6579AcrylamideHCID 8166Dodecanoyl chlorideHCID 88828N-HexadecylacrylamideHCID 6451240Aluminum(III) Chloride

生成物 1

HCID 10444995N-Dodecanoylacrylamide

試薬・触媒・溶媒 1

HCID 180Acetone溶媒

実験手順

In a 250 ml capacity conical flask 10.9 g dodecanoyl chloride (0.05 M), 3.5 g acrylamide (0.05 M) and 50 ml acetone were placed to obtain a clear solution. The solution was stirred with a magnetic needle at room temperature. 6.5 g anhydrous aluminium chloride (0.05 M) was added and the reaction mixture was stirred at room temperature. After 5 to 10 minutes of stirring, vigorous evolution of hydrogen chloride took place which ceased after about 5 minutes. The product was isolated following the procedure described for synthesis of N-cetylacrylamide.

後処理

  1. customto obtain a clear solution
  2. stirringthe reaction mixture was stirred at room temperature
  3. stirringAfter 5 to 10 minutes of stirring
  4. customThe product was isolated

出典と根拠

ORDレコード
ord-fed8b2f6195748bb83a847ae3540d487
出典データセット
uspto-grants-2002_04
特許番号
US06369249B1

関連ノート

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