関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Chlorotrimethylsilane | HCID 6397 | — |
| 反応物 | Linalool | HCID 6549 | — |
| 触媒 | Bismuthyl (ion) | HCID 5237718 | — |
| 生成物 | 1-Chloro-3,7-dimethyl-octa-2,6-diene | HCID 99106 | 83.2% |
反応手順
To a mixture of 170 g linalool and 20 mg bismuth(III)-oxide heated to 60° C., 130.5 g trimethylchlorosilane were dropped in. Then the mixture was cooled to room temperature and the organic layer was separated. The resulting oil was purified by distillation to yield 158.35 g of a colorless oil.
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06369248B1 |
|---|
| 出典データセット | uspto-grants-2002_04 |
|---|
| ORD ID | ord-93b7fdeaec43433281661a380319a923 |
|---|
| 出典メモ | uspto-grants-2002_04 |
|---|
