Acetone → Benzoic acid, 2-(1-methylethylidene)hydrazide
反応式
[C:1]([NH:9][NH2:10])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH3:11][C:12]([CH3:14])=O>>[CH3:11][C:12](=[N:10][NH:9][C:1](=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1)[CH3:14]参加物
3
反応条件
- 温度
- 5 °C
実験手順
A four neck flask (1 liter) equipped with a thermometer, a reflux condenser and a stirrer was charged with 136 g (1.0 mol) of benzohydrazide and 600 ml of acetone and then heated under reflux for 12 hours. The reaction liquid was cooled down to 5° C. or lower, and then crystal was filtered off and dried under reduced pressure, whereby white crystal was obtained.
後処理
- customA four neck flask (1 liter) equipped with a thermometer, a reflux condenser and a stirrer
- temperatureheated
- temperatureunder reflux for 12 hours
- customThe reaction liquid
- filtrationlower, and then crystal was filtered off
- customdried under reduced pressure, whereby white crystal
- customwas obtained
出典と根拠
- ORDレコード
- ord-e8b7f8ad3dd4478a8d5ef3d40e99e176
- 出典データセット
- uspto-grants-2002_04
- 特許番号
- US06380288B1
反応ノート
読み込み中…