関与物質
| 役割 | 名称 | HCID | 仕込み量 |
|---|
| 反応物 | Dinitrofluorobenzene | HCID 6264 | — |
| 反応物 | N-methyl-2-pyrrolidone | HCID 13387 | — |
| 反応物 | 3-(Heptadecafluorooctyl)aniline | HCID 4245356 | — |
| 溶媒 | Triethylamine | HCID 8471 | — |
| 生成物 | N-[3-(perfluorooctyl)phenyl]-2,4-dinitrobenzenamine | HCID 22735001 | 83.2% |
反応手順
A mixture of 3-(perfluoro-n-octyl)benzenamine (2.04 g), 2,4-dinitrofluorobenzene (0.78 g), NMP (8 mL) and triethylamine (0.85 mL) was heated to 70° C. for 16 hr. Extraction and recrystallization from hexane-ethyl acetate gave N-[3-(perfluorooctyl)phenyl]-2,4-dinitrobenzenamine (2.25 g, mp 124.5-125° C.).
情報源と証拠
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| 特許番号 | US06380432B2 |
|---|
| 出典データセット | uspto-grants-2002_04 |
|---|
| ORD ID | ord-45b562f6d5b84aa68080dedf0184c3b1 |
|---|
| 出典メモ | uspto-grants-2002_04 |
|---|
