Butanal → 2-Ethyl-5,7,7-trimethyloctanal

反応式

[CH3:1][CH:2]([CH2:6][C:7]([CH3:10])([CH3:9])[CH3:8])[CH2:3][CH:4]=O.[CH:11](=[O:15])[CH2:12][CH2:13][CH3:14]>>[CH2:13]([CH:12]([CH2:4][CH2:3][CH:2]([CH3:1])[CH2:6][C:7]([CH3:10])([CH3:9])[CH3:8])[CH:11]=[O:15])[CH3:14]

参加物

反応物 2

HCID 261Butanal

HCID 215743,5,5-Trimethylhexanal

生成物 1

HCID 201310352-Ethyl-5,7,7-trimethyloctanal

実験手順

2-Ethyl-5,7,7-trimethyloctanal was prepared from 3,5,5-trimethylhexanal and n-butanal similarly to Examples 1 and 2; it was obtained in the form of a diastereomeric mixture.

後処理

customit was obtained in the form of a diastereomeric mixture

出典と根拠

ORDレコード: ord-1ca315fdea9342118eb4946501177a7b
出典データセット: uspto-grants-1988_07
DOI: 10.6084/m9.figshare.5104873.v1
特許番号: US04758548

反応ノート

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