Phosgene → (2,2-Dimethyl-1,3-dioxolan-4-yl)methyl carbonochloridate
反応式
[C:1](Cl)([Cl:3])=[O:2].[CH3:5][C:6]1([CH3:13])[O:10][CH:9]([CH2:11][OH:12])[CH2:8][O:7]1>C1C=CC=CC=1.C(Cl)Cl>[Cl:3][C:1]([O:12][CH2:11][CH:9]1[CH2:8][O:7][C:6]([CH3:13])([CH3:5])[O:10]1)=[O:2]参加物
5
実験手順
10 ml of a 10% w/v solution of phosgene in benzene were added to a solution of 1.0 g of 2,3-isopropylideneglycerol in 5 ml of methylene chloride, and the mixture was allowed to react overnight at room temperature. The mixture was then concentrated by evaporation under reduced pressure, giving 1.47 g of the title compound as a liquid.
後処理
- customto react overnight at room temperature
- concentrationThe mixture was then concentrated by evaporation under reduced pressure
出典と根拠
- ORDレコード
- ord-d1a180b5d8e04457ad6e1d23b8c4e260
- 出典データセット
- uspto-grants-1988_07
- 特許番号
- US04760054
反応ノート
読み込み中…