Carbon Dioxide → Chlorine
反応式
[Cl:1][Cl:2].C(=O)=O.II.[SH:8][C:9]1[N:14]=[CH:13][CH:12]=[CH:11][N:10]=1>C(Cl)(Cl)(Cl)Cl>[Cl:1][Cl:2].[Cl:1][S:8][C:9]1[N:14]=[CH:13][CH:12]=[CH:11][N:10]=1参加物
7
実験手順
A solution of chlorine in CCl4 is prepared by condensing 4.38 ml liquified Cl2 at dry-ice temperature, and then adding 75 ml CCl4 at -10° to it. To this solution at 0° is added two small crystals of iodine, and then 10.0 g 2-mercaptopyrimidine in 35 ml CCl4 dropwise over 1.5 hours. After stirring another hour, the solvent, excess Cl2 and HCl are evaporated in vacuo, leaving 5.I as residue.
後処理
- customthe solvent, excess Cl2 and HCl are evaporated in vacuo
出典と根拠
- ORDレコード
- ord-31b39695e54b4b60a1ee80fab38c8cf8
- 出典データセット
- uspto-grants-1988_07
- 特許番号
- US04760067
反応ノート
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