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HRID 846013作成日:2026年10月27日

Benzyl Chloride → 2-Benzyltoluene

https://huagongshe.com/reaction/846013

反応式

関与物質

役割名称HCID仕込み量
反応物Benzyl ChlorideHCID 7503—
溶媒TolueneHCID 1140—
生成物2-BenzyltolueneHCID 69738—
生成物Methylbis(phenylmethyl)benzeneHCID 3034397—

反応手順

In the like manner as the example in the above reference, benzyl chloride and toluene were reacted in the presence of a catalyst of FeCl3 ; and benzyltoluene and dibenzyltoluene were obtained by distillation. These benzyltoluene and dibenzyltoluene in a weight ratio of 80:20 were mixed together. The contents of isomers of the benzyltoluene in the obtained mixture were o-isomer: 39.1 wt %, m-isomer: 5.4 wt % and p-isomer: 35.5 wt %, which were almost coincident with the analytical values of the above JARYLEC C-100 of o-isomer: 36.2 wt %, m-isomer: 5.9 wt % and p-isomer: 37.8 wt %.

情報源と証拠

DOI10.6084/m9.figshare.5104873.v1
特許番号US05134761
出典データセットuspto-grants-1992_08
ORD IDord-c55e4a3247e04bc9be651106a16733a4
出典メモuspto-grants-1992_08